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关联氧化物的离子调控与物态设计

Ionic manipulation and the design of emergent states in correlated oxides

  • 摘要: 关联氧化物中电荷、自旋、轨道和晶格等多自由度间的强关联耦合,孕育了丰富的关联电子态,为下一代信息与能源技术提供了重要材料平台。近年来,离子调控作为一种新兴的物性调控策略,通过驱动离子在晶格中的迁移、嵌入、脱出与取代,实现了量子材料中化学组成、晶体结构、局域配位环境及关联电子态的协同重构,为亚稳态物相构筑和新奇量子物态设计提供了新的研究思路。文章简要介绍关联氧化物中离子调控的研究进展,重点阐述氧离子的加氧/减氧调控、氢负离子取代以及质子嵌入等典型调控策略,讨论在电荷补偿、结构重构及关联电子态演化等方面的物理机制。最后总结离子调控领域当前面临的主要挑战,并展望其在关联电子态与新奇物态设计以及新型功能器件中的应用前景。

     

    Abstract: Correlated oxides provide one of the richest platforms for exploring emergent quantum phenomena arising from strong coupling among charge, spin, orbital, and lattice degrees of freedom. Over the past few decades, ionic manipulation has emerged as a versatile strategy for tailoring correlated oxides. By driving the migration, insertion, extraction, and substitution of mobile ions, ionic manipulation enables the dynamic reconstruction of chemical composition, crystal structure, local coordination environments, and electronic states, providing new opportunities for stabilizing metastable phases and engineering emergent correlated quantum states. This review summarizes recent advances in the ionic manipulation of correlated oxides, with particular emphasis on oxygen-ion insertion/extraction, hydride substitution, and proton intercalation. We discuss the underlying mechanisms governing these ionic processes, including charge compensation, structural reconstruction, local crystal-field modulation, and correlated electronic-state evolution, together with their implications for iontronic functionalities. Finally, we highlight the major challenges and future opportunities for this exciting field.

     

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