Block copolymers: a beautiful encounter among physics, chemistry, biology, and engineering
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摘要: 基于过去三十年的不断探索，嵌段共聚物已成为研究分子自组装和相关基本现象的理想模型体系。定量化理论预测和精确实验观察的携手，使得对于嵌段共聚物平衡态相行为的理解已达成一致，并对于从分子组成到介观相结构，再到宏观材料性质的关联与机理有了比较完整的理解。文章回顾目前理解嵌段共聚物相行为的物理模型及其基本假设，并对嵌段共聚物在物理、化学、生物、工程等学科的研究进行展望。Abstract: Based on important advances over the last few decades, block copolymers have been established as an excellent physical model system for studying molecular self-assembly and related fundamental phenomena. Good agreement between the quantitative theory and accurate experiments on the equilibrium phase behaviour of block copolymers has been achieved, and a thorough understanding has emerged by connecting the microscopic constituents to the mesoscopic phase structures and macroscopic material properties. Here, we review our current understanding of block copolymer phase behaviour, the standard model with its underlying assumptions, and present an overview of future applications in various fields such as physics, chemistry, biology, and engineering.
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Keywords:
- block copolymer /
- self-assembly /
- phase diagram /
- self-consistent field theory
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